5/24/2023 0 Comments Complexed ion bonding![]() Sodium cyclopentadienide (NaCp) and lithium cyclopentadienide are commonly used. The compounds are generally prepared by salt metathesis reactions of alkali-metal cyclopentadienyl compounds with transition metal chlorides. Moreover, inverse sandwich compounds with the "metal–Cp–metal" structures are known. Such complexes, sometimes called "slipped Cp complexes", are invoked as intermediates in ring slipping reactions. In these η 3-Cp complexes, the bonding resembles that in allyl ligands. Still rarer, the Cp unit can bond to the metal via three carbons. It is probable that η 1-Cp complexes are intermediates in the formation of η 5-Cp complexes. Typical examples of this type of complex are group 14 metal complexes such as CpSiMe 3. ![]() These types of interactions are described as σ-complexes because they only have a σ bond between the metal and the cyclopentadienyl group. In relatively rare cases, Cp binds to metals via only one carbon center. ![]() Almost all of the transition metals employ this coordination mode. These complexes are referred to as π-complexes. The M–Cp bonding arises from overlap of the five π molecular orbitals of the Cp ligand with the s, p, and d orbitals on the metal. This bonding mode is called η 5-coordination. Monometallic compounds featuring only one Cp ring are often known as half sandwich compounds or as piano stool compounds, one example being methylcyclopentadienylmanganese tricarbonyl (CpMn(CO) 3).Īll 5 carbon atoms of a Cp ligand are bound to the metal in the vast majority of M–Cp complexes. One widely studied example is the Fp dimer, (Cp 2Fe 2(CO) 4). Mixed-ligand Cp complexes containing Cp ligand and one or more other ligands. Metallocenes are often thermally stable, and find use as catalysts in various types of reactions. Some are catalysts for ethylene polymerization. Bent metallocenes are represented by compounds of the type. This area of organometallic chemistry was first developed in the 1950s. When the Cp rings are mutually parallel the compound is known as a sandwich complex. A famous example of this type of complex is ferrocene (FeCp 2), which has many analogues for other metals, such as chromocene (CrCp 2), cobaltocene (CoCp 2), and nickelocene (NiCp 2). Examples īiscyclopentadienyl complexes are called metallocenes. The metal–cyclopentadienyl interaction is typically drawn as a single line from the metal center to the center of the Cp ring. Cyclopentadienyl ligands almost invariably bind to metals as a pentahapto ( η 5-) bonding mode. Zirconocene dichloride, a cyclopentadienyl complexĪ cyclopentadienyl complex is a coordination complex of a metal and cyclopentadienyl groups ( Cĥ, abbreviated as Cp −).
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5/24/2023 0 Comments Neon drive game platforms![]() ![]() It seems like you spent a bit of time to get that to work and then not have it utilized as much. I was expecting the store to pop up a couple more times. You were on to something good, and I was waiting for a bit more game to fully flesh out the chaos, but the game ended right when I felt like it was gonna get good. The movement and jumping were a bit janky at times and I had some trouble going the way I wanted to go at some points. However the core gameplay itself could've used a bit more love. You did have a great settings menu that helped a good deal with accessibility, and the menus were all completed so the player could poke around a bit before jumping in. But, having the player discover what each of these things do through gameplay wouldve gone such a long way. I did appreciate that being there and it helped me prepare for what was to come. I feel like you should find a way to tutorialize the player better on what each of the enemies, obstacles and pickups do instead of just having the text above each thing. However, the intro area to the level looks like something out of Gmod. I did appreciate the tutorial right before you start so you get all the controls thrown at you before you get in there. There's a lot of room for improvement here, especially with the lack of a gunshot sfx. 5/24/2023 0 Comments Bear valleyJohn Wong and the rest of the family were interviewed and, he voluntarily took a lie detector test and authorities subsequently confirmed that he was not a suspect. ''But if she's here, she's not able to respond to us.'' Two days later, the search was called off a winter storm brought in heavy snow and officials told the family that the chances of surviving such a storm were slim to none. After such a significant search for Katherine, the authorities believed she may have met with foul play or left the resort. ''There are no tracks going out, except for animal tracks,'' Deputy Sheriff Matt Streck said. The Alpine County Sheriff's Department and Bear Valley ski patrols searched for her with the assistance of two helicopters, ten winter-trained dog teams, and about 50 search experts from nearly a dozen law enforcement agencies. John and their son looked for Katherine for about 30 minutes and then notified resort officials that she had gone missing. She had black hair with brown eyes, was 5 feet 4 inches tall, and weighed about 118 pounds. Wong was wearing a light gray jacket and light blue pants and ski boots when she disappeared. When John reached the bottom of the slope his wife was nowhere to be seen. Katherine ate lunch with the group at about 11.30 am and skied for the next few hours with her husband, whilst the kids went with their adult cousin.Ībout 3.45 pm, Katherine took a ski lift up the mountain with her husband, but then they separated and she took a different path down using the Mokelumne West Run, an intermediate slope. It was the family's first visit to Bear Valley, as they had heard it was one of the quieter resorts. It has more than 75 trails, 1,680 skiable acres, and 1,900 feet of vertical drop, all serviced by a total of ten lifts. It is located on Highway 4 between Lake Tahoe and Yosemite in the Central Sierra Nevada Mountain Range and is described as a family-friendly resort that accommodates skiers and riders of all levels and abilities. Katherine Wong was last seen on February 19, 1999, at the Bear Valley ski resort, south of Lake Tahoe. Katherine Wong’s trip to Bear Valley Ski Resort She was an intermediate-level skier and visited California's ski resorts on a regular basis.įour months later, Katherine’s body finally turned up. ![]() ![]() Wong had gone skiing with her husband, 52-year-old pediatric dentist John Wong, two relatives, and two of her three children, a 9-year-old daughter and a 13-year-old son. She was a San Jose pediatrician who mysteriously disappeared from the Bear Valley Ski Resort, south of Lake Tahoe in California.ĭr. Dr Katherine Wong, Disappeared February 19th, 1999, Body found June 10th, 1999, Bear Valley Ski Resort, California.ĭr. Katherine Wong, 48, lived in Milpitas, a city in Santa Clara County, California, in Silicon Valley. 5/24/2023 0 Comments Default folder x big surThere’s also smarter handling of Finder windows when you have more than one “Finder” running (meaning you’re also using Path Finder or ForkLift), some additional “hidden preferences” (see the release notes – the documentation’s being updated now, so doesn’t show them yet) and some important bug fixes.įull details and download links are on the Default Folder X Release Page. ![]() It’s not an enormous change, but it does integrate more smoothly with Big Sur. As you may have seen in the beta releases, Default Folder X has a new app icon and new toolbar icons all around. I’ve tried to be an equal-opportunity cloud supporter: This feature works with iCloud, Dropbox, Google Drive, OneDrive and Box Sync.Īlong with updating Default Folder X’s internals to work with Big Sur’s Finder and Open / Save dialogs, this release also updates its look to fit in with Big Sur’s iOS-ish look and feel. ![]() So if your coworker updates a document in a shared Dropbox folder and then accosts you on Slack to review it, you can just select it straight from your Recent Files menu. If something gets synced to your Dropbox or OneDrive folder, the changes will appear immediately in Default Folder X’s Recent Files and Recent Folders menus. Clair Software issued version 5.6.6 shortly after this release to correct a problem that resulted in Default Folder X not being shown in the Automation section of the macOS privacy settings when freshly installed (preventing the Finder-click feature from working and causing Default Folder X to complain about permissions). ![]() Default Folder X now keeps track of changes in shared folders that are synced from the cloud. One new feature is nearly invisible, but can be super convenient. 5/24/2023 0 Comments Pasta fazool![]() It all starts with some olive oil, onion, carrot, celery and garlic. The origins of this pasta e fagioli soup can be traced back to rural Italy, and what I love most is that this humble recipe turns just a handful of ingredients into a terrific family meal.Ī perfect combination of pasta, beans, vegetables, and a flavorful tomato broth. Seriously, it’s unbelievable how good and filling it is! Rich, full of fluffy beans and with a thick creamy broth that is everything. This is one pot wonder, the kind of meal that makes you feel warm and cozy inside. This pasta e fagioli soup is a must in every Italian family and it has been one of my staples for as long as I can remember. Have it with your favorite red wine.I’m excited to share this simple yet iconic pasta recipe with you all. And ps, I am not picking on Olive Garden….certainly I’ve enjoyed quite a few meals there over the years. But in my opinion this version is the best. The recipes can vary from town to town in Italy, some being thick and some being more watery. It is a traditional “peasant dish” made up of ingredients that were inexpensively available in Italy. So what does pasta fazool, err, fagioli, even mean? Pasta e Fagioli translates to pasta and beans. You will want to savor every last drop of the broth, some bread on the side will help you get it done. Another trick: don’t forget a few slices of crispy Italian bread for dipping. Be careful with the amount of pasta or it won’t turn out quite right. Do it well and your broth will shine bright! Too much pasta will absorb the broth, and leave you with a dry soup, or really just a pasta dish. Make no mistake, the broth is the star of this soup. You really want those flavors imparted in your broth. Like many Italian dishes, you start building the flavors with chopped onions and minced garlic sauteed in extra virgin olive oil. But done just right, this recipe offers up the perfect creamy salty texture for its broth, and without the cream, yay! Without it, it really just reverts to pasta and tomato sauce. You have to do the bean puree to really get the taste right, in my opinion. This relies more heavily on the cannellini beans to thicken up the broth, rather than tomato sauce. This is an authentic bean puree version of the dish. This recipe is not the recipe for your Olive Garden version of pasta fazool. In Greenville, the best I have had was at Da Vinci’s Ristorante on Pleasantburg Drive, but quite frankly, it is not exactly widely available. ![]() Last I was at Bamonte’s, it wasn’t on the menu, but you can request it. Who had the best pasta fazool? Villa Grazia in Centereach, Branchinelli’s in Hauppauge, or Bamonte’s in Brooklyn were the don’t miss versions. Not places like the Olive Garden, but the sort’ve “hole in the wall” places that only the locals would know about. Yes, most of our date nights were at Italian restaurants. Okay, back to my wife and I’s love of pasta fazool. ![]() Sausage and Bean Soup with Escarole – Another Great Italian Soup! The garlic, the broth, the salt, the beans, and the pasta just come together to provide a magnificent soup! The inventors of pasta fazool over there in Italy sure knew what they were doing. My wife and I absolutely love pasta fazool! When we lived back on Long Island in New York, authentic pasta fazool was our go-to appetizer whenever we had a date night. I think Dean Martin knew from experience when he sang “When the stars make you drool, just like pasta fazool, that’s amore.” Can you beat a piping hot bowl of authentic pasta fazool, err, fagioli, on a cold and rainy winter day, or anytime for that matter? Not really! 5/24/2023 0 Comments Youtube base64 encoding![]() Instantly, we can see it begins with PowerShell executing a base64 encoded string. This means we need to review the threat details and attempt to figure out if this alert is legitimate or not.įirst we can review the Attack Story information in the Raw Data section of the SentinelOne console: Given that this is a Fileless attack there is no hash reputation available via third party validation tools. In this case, we have an alert regarding a PowerShell command. First, we take a look at an attack sequence the first place I always look (if the process is there) will be PowerShell: So let’s see how this could help us to understand an actual attack on the network. ::ASCII.GetString(::FromBase64String($coded_string)) | Out-File -Encoding "ASCII" base64_out.txt ::ASCII.GetString(::FromBase64String($coded_string)) $coded_string = "SG9va2VkIG9uIHBob25pY3Mgd29ya2VkIGZvciBtZQo=" > ::UTF8.GetString(::FromBase64String('SG9va2VkIG9uIHBob25pY3Mgd29ya2VkIGZvciBtZQo='))Īs we did with Python above, we can replace the one-liner CLI with a PowerShell script if we wish: # Replace the quoted text with the code you wish to decrypt. We can swap out ASCII for UTF-8 if we prefer: > ::ASCII.GetString(::FromBase64String('SG9va2VkIG9uIHBob25pY3Mgd29ya2VkIGZvciBtZQo=')) # Print the decryption output to the screen. # Replace the quoted text with the code you wish to decrypt.Ĭoded_string = 'SG9va2VkIG9uIHBob25pY3Mgd29ya2VkIGZvciBtZQo='Ĭode_dump = base64.b64decode(coded_string) We can achieve the same thing with a Python script like this: #!/usr/bin/env python $: echo "SG9va2VkIG9uIHBob25pY3Mgd29ya2VkIGZvciBtZQo=" | base64 -decode On macOS/Linux with Bash (CLI) it’s the same process, but this time we specify the -decode option: SG9va2VkIG9uIHBob25pY3Mgd29ya2VkIGZvciBtZQo= Decoding Strings > ::ToBase64String(::UTF8.GetBytes("Hooked on phonics worked for me")) ![]() On Windows, we can encode a string with PowerShell (CLI): $: echo "Hooked on phonics worked for me" | base64 ![]() On macOS/Linux with Bash (CLI) we can simply echo the target string and pipe it to the base64 utility: ![]() Let’s take a look at not only decrypting but also encrypting because, who knows? Maybe one day you will need or want to know both sides of the process. If the string contains special characters like “+” or “/” then there is a good chance the string will decode into something like a compressed file or image.Ī good rule of thumb for this is to decrypt the string on the command line, and if you cannot read the output then try writing it to a file and use something like Detect It Easy (D.I.E.) to determine how you can view the file contents.ĭecryption is extremely easy and can be done on any OS.If the string does not contain any special characters other than “=” then there is a good chance that it will be plain text when decrypted.There are a few things that I like to look for with base64 strings: The wiki article here goes into more details about the background of the encoding’s implementation and history, but here we’ll focus on the practical aspects within a security context. These strings must also be divisible by 4 to be well-formed. There are 64 characters in the Base64 “alphabet”, and an encoded string will contain a mixture of uppercase and lowercase letters, numbers, and sometimes an “=” or two (never more than two) at the end. VGhpcyBpcyB3aGF0IGJhc2U2NCBsb29rcyBsaWtlIGluIHRoZSB3aWxkLgo= These are the methods that I use to both encode and decode in my daily work.Ī base64 string is pretty easy to identify: In this article, I will share both a simple and a slightly more advanced understanding of Base64 encoding. The most common methods are not terribly hard to learn and will help you to make better decisions on the legitimacy of a command or call seen on your network. Understanding the encoding methods threat actors use can help not only in everyday operations but importantly in cybersecurity and network security contexts. They are also widely used by malware authors to disguise their attacks and to implement anti-analysis techniques designed to frustrate malware hunters and reverse engineers. Encoded strings are everywhere and have many legitimate uses across the technology sector. 5/23/2023 0 Comments Angry rimuru tempest![]() Only available once the target has been fully Analyzed. Mimicry - Allows Rimuru to reproduce the form and Skills of absorbed targets.Its space is roughly 10x that of Gluttony’s. Items stored in the user's stomach are unaffected by time. It can also store materials created via Analysis. Compared to its Unique Skill counterpart: "Gluttony", it has been improved and can now ignore space and time to consume anything in the user's perception. spiritual life forms like Elementals and Daemons), as well as Skills, Magic, Aura, and any projectile-type attacks of the aforementioned categories, as well as magicules themselves. "Predation" can be used on organic, inorganic, and non-physical objects (e.g. The chance of success is lowered if the target has a consciousness of any kind. ![]()
5/23/2023 0 Comments Watch artoon online![]() If you have any suggestions to Watch Cartoon Online that we should add to this Best Cartoons Watch Online Sites List, feel free to contact us at, we always welcome new ideas. If you looking for apps to watch cartoon, you can try the official cartoon network app and best of all Youtube app itself.Īlso Read: What Song Is This? Best Song Finder Apps So, this was our list of the best websites where you can watch cartoon online. Or maybe if you are still a cartoon lover like me, you can go ahead and watch the recent ones that have been on the air for a long time now. Choose that episode and relive those childhood memories. It would be pretty great if each one of them had all of the perks and pros of each other so in my opinion, if you have a hankering for a show to watch, choose any platform of your choice. This would be a tough decision to choose the best one out of these. My Thoughts: Best Website to Watch Cartoon Online So in order to maintain your security, never share personal details on any website to watch cartoon online. Yes, they are mostly safe but you can’t expect 100% protection anyway. But the sites do have their own policies and tricks up their sleeves to escape most of the legal trouble coming their way.Īlso Read: 10 Best Online Games You Can Play With Friends Over The Internetīottom line, as long as you are not downloading, purchasing, or selling any kind of digital copyrighted content you are probably safe to watch these cartoons or animes on the sites mentioned. But the sites hosting them might face some legal actions in case some organization or the original owner of those shows claim or file any complaint against them. It’s not illegal to watch cartoon online. ![]() There are sing-a-longs, Daisy and Ollie and Curious George as well to keep their funny bones tickled till the end.Ĭlick Here Is watching cartoons on free sites illegal? If you want your kid to be engaged for a while and have a good time with them, we would highly recommend checking this out as it has got it all. The best part is that there are no bugging ads or distractions that might ruin your watching experience. They have multiple games for kids on their website.Īlso Read: 10 Best Free Texting Apps for Android ![]() The most famous “Thomas and Friends” is also available for watching on their platform. Fireman Sam, Super Wings, Mush-Mush and the muscles, Masha and the Bear, Cocomelon are some of the popular cartoon shows available on their website. It is one of the best websites to watch cartoon online that offer the cutest and best collections of old and new cartoons that will bring back so many memories from your childhood. It does not matter if you are a child or a 26-year-old adult. If you ask me how to download watch cartoon online videos? This is one of the Best website to watch cartoon online. It is easy to use the platform and offers a wide range of cartoon shows and anime videos. You can search for cartoon shows and anime shows and the site will list down the various options as per your search. It is used by the majority of the people as it is easy to find almost any video from this site just by using the Search Bar of this site. YouTube is one of the most popular platforms to watch cartoon online. My Thoughts: Best Website to Watch Cartoon Onlineīest Website to Watch Cartoon Online 2023 1. ![]() Is watching cartoons on free sites illegal?.Best Website to Watch Cartoon Online 2023. 5/23/2023 0 Comments Incontrol sc2![]() Reddit – Geoff 'iNcontroL' Robinson has passed away. I don't think any of that would have happened if he would'nt have taken the time to talk to me." -u/Nagabe Search Interest I lost 130 pounds, got confident, started powerlifting, and got married. 00 Sale ST1 - Substrate tray for SC1 and SC2 model cages. I struggled with weight all my life (340 pounds when I met him) and he gave me tips on dieting, lifting weights, and gaining confidence. There are plenty of options to make you feel empowered and in control of your build to order. If you actually do watch these series, you will realize that the thing that allows them to be good with low APM is having good decision making from experience and confidence. …"I met him at MLG Columbus years ago and it actually changed my life. You can work on both of these factors to improve at sc2, but improving your APM is a lot more straightforward than improving the efficiency. Reddit users also expressed condolences for the passing of Robinson. These included tweets by LiquidNazgul (shown below, left), esportsstarcraft (shown below, center) and (shown below, right). Many Twitter users would respond with mourning towards iNcontroL's untimely death. A thread about his passing was posted in the Team Liquid forums, where users offered their condolences and well wishes. The Starcraft community mourned for iNcontroL's death. ![]() His sudden passing led to an outpouring of support from the gaming and StarCraft community. On July 21st and 22nd, 2019, iNcontroL's social media accounts announced that Robinson has passed away due to pulmonary embolism, or lodging in the lung arteries. This would later become petitioned on Reddit and later implemented into Twitch. His facial expression was purposely created to express his most grotesque faces. The emote references to a time when he was growing his hair out and asked his make-up lady to gel his hair this way before hosting a podcast. He is also the face of a Twitch emote called TheThing is a global Twitch emote. INcontroL grew popular on Twitch, garnering over 114,000 subscribers before his passing. He would also participate in podcasting, and appeared on shows such as State of the Game hosted by JP "itmeJP" McDaniel until leaving in, and The Pylon Show co-hosted by Dan "Artosis" Stemkoski. iNcontroL would pursue content creation, streaming on Twitch and casting for Starcraft II tournaments. iNcontroL led the team from 2010 until they disbanded in 2017. He joined the team Evil Geniuses in 2009 and would later become their captain. iNcontroL was well known as an American competitor in Starcraft II and formerly Brood War. INcontroL was born on September 11th, 1985 and was from Seattle, Washington. INcontroL, or known as Geoffrey Robinson, was a gamer who was recognized as a Starcraft II player and online personality. 5/23/2023 0 Comments Learn to fly 3 steam beta codes![]() This version will work on Chrome OS and any computer with the Chrome browser. Version 2.0.0 now supports DJI Tello! You can connect directly to Tello from your computer and fly autonomous missions. Better command handling for more successful missionsĭroneBlocks 2.2.0 fixes bug with "Create variable"ĭroneBlocks 2.1.1 adds number rounding for variables in navigation blocksĭroneBlocks 2.1.0 includes a curve flight block for Tello This can be found in the menu under "Switch to Metric Units" Support for metric units as the default. Unit conversion for telemetry to display in centimeters or inches Telemetry includes altitude, Time of flight (ToF) distance between Tello and object beneath, pitch attitude, roll attitude, and yaw attitude Saved missions will automatically be synced when device comes back online. Support for offline storage and retrieval of missions! User must be logged in before going offline. Ability to login and save/retrieve missions with a non-Google account Fix for Tello missions page linking to iOS canvas This is a great way to watch your code line by line while Tello flies. Blocks will highlight as Tello performs its mission. Then you will have the choice of selecting Tello, Tello EDU, or Tello Talent for programming with DroneBlocks! ![]() You can find the Tello Talent coding blocks by going to the menu and accessing "Select Drone Type". Support for Tello Talent (Robomaster TT) main LED and matrix LEDs. Drone coding fix for Tello Talent delay between individual matrix LED commands and flight commands Official keyboard flight control! Be sure to connect to Tello first and then click the "Keyboard Control" button to follow the instructions. Flip with arrow keys: forward, backward, left, right So keep looting and killing, and don't forget to level up your Skill Deck for maximum zombie-slaying potential!ĭead Island 2 will release on 21 April 2023 for PlayStation 4|5, Xbox One, Xbox Series X|S, and Windows PC (via Epic Games Store) and is currently available to pre-order.Teaching STEAM with block coding and drones DroneBlocks 3.9 () But be warned: pairing the wrong Skill Cards for your Slayer can end disastrously if you aren't careful. Overall, the new Skill Deck system in Dead Island 2 offer a plethora of unique abilities and attributes that can greatly enhance your gameplay experience. (Picture: Deep Silver) Where To Find Skill Cards In Dead Island 2īut where can you find Skill Cards in Dead Island 2? Fortunately, finding these combat-enhancing cards is relatively straightforward: simply loot around the blood-stained streets of Hell-A or smash some zombie brains to earn special Skill Cards. You can find Skill Cards at various locations throughout Hell-A. More specific details about the Survivor, Slayer, and Numen cards remain scarce however, we will update this page with further information later on. Some examples of Ability Cards include Dodge and Drop Kick, which allows players to regain stamina and stun zombies with well-timed dodges, leaving them open to counter-attacks or to perform a powerful jump kick attack that sends zombies flying, respectively. For example, as demonstrated in the Extended Gameplay Trailer, Dani's Thunderstruck card add a forceful explosion on impact on Heavy Attacks, while Bloodlust allows Dani to regain HP when slaying multiple zombies in quick succession. These cards cannot be swapped out and provide exceptionally powerful abilities that players can pair with other Skill Cards in the game. It's worth noting that there are also Innate Skill Cards in Dead Island 2 that are unique to individual Slayers. This gives players the freedom to customize their character and playstyle to their liking or adjust to niche situations in the game "on the fly." Skill Cards replace Slayers' traditional Skill Tree in Dead Island 2. Note: We will update this guide with more detailed information about the new Card Deck system in Dead Island 2 once more information is revealed by the developers.ĭead Island 2 Skill Deck System: Skill Cards Explainedįirst things first: What is the Skill Deck system in Dead Island 2? In simple terms, Skill Cards allow players to enhance the combat abilities and attributes of their Slayers to "help level the playing field." The cards are divided into four categories: Abilities, Survivor, Slayer, and Numen, which can be swapped out and combined at any moment in the game. |